It is because in the second screenshot you're hosting the server as Host (directly from the game) while in the first screenshot you're hosting the server as Dedicated.
The fact that "Server Settings" is not shown in the first image it should not matter whatsoever. Once you set up the RCon password correctly you're already able to tweak your server through console commands. Please check the list of all the available CS2D commands on how to tweak your server.
I told you that once you type your RCon password correctly to gain administration privileges you can tweak your server by using the CS2D commands available from the list I gave you from the previous post. Especially these ones.
Or if you don't want to waste all the time typing the commands manually via console then get an administration script such as The Admin Script v4.0.2 Final (342).
@ Stinger: But even so, I can not configure the server by pressing ESC and I can not even put it in the sv_restartround console on the console that does not pick up.